Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand.
نویسندگان
چکیده
The diastereoselective formation of a meso-dinuclear Ru(ii) complex of a novel bis-bidentate ligand is reported along with its electrochemical and photophysical properties. The design of the ligand, with its parallel coordination vectors, induces a diastereoselectivity of 1 : 13 : 1 [ΛΛ : (ΛΔ or ΔΛ) : ΔΔ] for the dinuclear complex.
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عنوان ژورنال:
- Chemical communications
دوره 50 25 شماره
صفحات -
تاریخ انتشار 2014